{2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate

The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol­ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol­ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of th...

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Detalles Bibliográficos
Autores principales: Wan Nazihah Wan Ibrahim, Shamsuddin, Mustaffa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961822/
https://www.ncbi.nlm.nih.gov/pubmed/21202771
http://dx.doi.org/10.1107/S1600536808017078
Descripción
Sumario:The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol­ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol­ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of the tetra­dentate Schiff base dianions. The ethanol mol­ecule takes part in an O—H⋯O hydrogen bond. In the crystal structure, mol­ecules are stacked approximately along the b-axis direction. The O atom and three H atoms of the solvent molecule are disordered over two positions; the site occupancy factors are ca 0.8 and 0.2.

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