{2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate

The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol­ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol­ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of th...

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Autores principales: Wan Nazihah Wan Ibrahim, Shamsuddin, Mustaffa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961822/
https://www.ncbi.nlm.nih.gov/pubmed/21202771
http://dx.doi.org/10.1107/S1600536808017078
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author Wan Nazihah Wan Ibrahim,
Shamsuddin, Mustaffa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Wan Nazihah Wan Ibrahim,
Shamsuddin, Mustaffa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Wan Nazihah Wan Ibrahim,
collection PubMed
description The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol­ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol­ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of the tetra­dentate Schiff base dianions. The ethanol mol­ecule takes part in an O—H⋯O hydrogen bond. In the crystal structure, mol­ecules are stacked approximately along the b-axis direction. The O atom and three H atoms of the solvent molecule are disordered over two positions; the site occupancy factors are ca 0.8 and 0.2.
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spelling pubmed-29618222010-12-30 {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate Wan Nazihah Wan Ibrahim, Shamsuddin, Mustaffa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol­ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol­ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of the tetra­dentate Schiff base dianions. The ethanol mol­ecule takes part in an O—H⋯O hydrogen bond. In the crystal structure, mol­ecules are stacked approximately along the b-axis direction. The O atom and three H atoms of the solvent molecule are disordered over two positions; the site occupancy factors are ca 0.8 and 0.2. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961822/ /pubmed/21202771 http://dx.doi.org/10.1107/S1600536808017078 Text en © Ibrahim et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wan Nazihah Wan Ibrahim,
Shamsuddin, Mustaffa
Chantrapromma, Suchada
Fun, Hoong-Kun
{2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title_full {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title_fullStr {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title_full_unstemmed {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title_short {2,2′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(II) ethanol hemisolvate
title_sort {2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato}palladium(ii) ethanol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961822/
https://www.ncbi.nlm.nih.gov/pubmed/21202771
http://dx.doi.org/10.1107/S1600536808017078
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AT chantraprommasuchada 2222dimethylpropane13diylbisnitrilomethylidynediphenolatopalladiumiiethanolhemisolvate
AT funhoongkun 2222dimethylpropane13diylbisnitrilomethylidynediphenolatopalladiumiiethanolhemisolvate

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