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Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV)
In the molecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methylpyrazine-2-carboxylate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961826/ https://www.ncbi.nlm.nih.gov/pubmed/21202741 http://dx.doi.org/10.1107/S1600536808016139 |
Sumario: | In the molecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methylpyrazine-2-carboxylate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octahedral coordination is completed by an N atom of one of the 5-methylpyrazine-2-carboxylate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. |
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