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Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV)
In the molecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methylpyrazine-2-carboxylate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961826/ https://www.ncbi.nlm.nih.gov/pubmed/21202741 http://dx.doi.org/10.1107/S1600536808016139 |
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author | Gao, Zhongjun |
author_facet | Gao, Zhongjun |
author_sort | Gao, Zhongjun |
collection | PubMed |
description | In the molecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methylpyrazine-2-carboxylate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octahedral coordination is completed by an N atom of one of the 5-methylpyrazine-2-carboxylate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. |
format | Text |
id | pubmed-2961826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618262010-12-30 Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) Gao, Zhongjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methylpyrazine-2-carboxylate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octahedral coordination is completed by an N atom of one of the 5-methylpyrazine-2-carboxylate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961826/ /pubmed/21202741 http://dx.doi.org/10.1107/S1600536808016139 Text en © Zhongjun Gao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Zhongjun Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title | Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title_full | Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title_fullStr | Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title_full_unstemmed | Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title_short | Bis(5-methylpyrazine-2-carboxylato)diphenyltin(IV) |
title_sort | bis(5-methylpyrazine-2-carboxylato)diphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961826/ https://www.ncbi.nlm.nih.gov/pubmed/21202741 http://dx.doi.org/10.1107/S1600536808016139 |
work_keys_str_mv | AT gaozhongjun bis5methylpyrazine2carboxylatodiphenyltiniv |