Cargando…

Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)

In the mol­ecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methyl­pyrazine-2-carboxyl­ate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa...

Descripción completa

Detalles Bibliográficos
Autor principal: Gao, Zhongjun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961826/
https://www.ncbi.nlm.nih.gov/pubmed/21202741
http://dx.doi.org/10.1107/S1600536808016139
_version_ 1782189075322634240
author Gao, Zhongjun
author_facet Gao, Zhongjun
author_sort Gao, Zhongjun
collection PubMed
description In the mol­ecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methyl­pyrazine-2-carboxyl­ate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa­hedral coordination is completed by an N atom of one of the 5-methyl­pyrazine-2-carboxyl­ate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers.
format Text
id pubmed-2961826
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29618262010-12-30 Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV) Gao, Zhongjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methyl­pyrazine-2-carboxyl­ate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa­hedral coordination is completed by an N atom of one of the 5-methyl­pyrazine-2-carboxyl­ate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961826/ /pubmed/21202741 http://dx.doi.org/10.1107/S1600536808016139 Text en © Zhongjun Gao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhongjun
Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title_full Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title_fullStr Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title_full_unstemmed Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title_short Bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(IV)
title_sort bis(5-methyl­pyrazine-2-carboxyl­ato)­diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961826/
https://www.ncbi.nlm.nih.gov/pubmed/21202741
http://dx.doi.org/10.1107/S1600536808016139
work_keys_str_mv AT gaozhongjun bis5methylpyrazine2carboxylatodiphenyltiniv