2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate

In the organic mol­ecule of the title compound, C(19)H(25)O(2)P·0.5H(2)O, the benzene rings are oriented at a dihedral angle of 54.04 (3)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of two five-membered planar rings, which are oriented with respect to the adjacent benzene rings at...

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Detalles Bibliográficos
Autores principales: Chu, Qing-Yan, Liu, Shan, Liu, Yuan-Yuan, Chen, Wei, Zhu, Hong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961830/
https://www.ncbi.nlm.nih.gov/pubmed/21202868
http://dx.doi.org/10.1107/S1600536808016681
Descripción
Sumario:In the organic mol­ecule of the title compound, C(19)H(25)O(2)P·0.5H(2)O, the benzene rings are oriented at a dihedral angle of 54.04 (3)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of two five-membered planar rings, which are oriented with respect to the adjacent benzene rings at dihedral angles of 2.66 (3) and 2.79 (3)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules. The water oxygen atom lies on a twofold rotation axis.

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