2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate

In the organic mol­ecule of the title compound, C(19)H(25)O(2)P·0.5H(2)O, the benzene rings are oriented at a dihedral angle of 54.04 (3)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of two five-membered planar rings, which are oriented with respect to the adjacent benzene rings at...

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Detalles Bibliográficos
Autores principales: Chu, Qing-Yan, Liu, Shan, Liu, Yuan-Yuan, Chen, Wei, Zhu, Hong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961830/
https://www.ncbi.nlm.nih.gov/pubmed/21202868
http://dx.doi.org/10.1107/S1600536808016681
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author Chu, Qing-Yan
Liu, Shan
Liu, Yuan-Yuan
Chen, Wei
Zhu, Hong-Jun
author_facet Chu, Qing-Yan
Liu, Shan
Liu, Yuan-Yuan
Chen, Wei
Zhu, Hong-Jun
author_sort Chu, Qing-Yan
collection PubMed
description In the organic mol­ecule of the title compound, C(19)H(25)O(2)P·0.5H(2)O, the benzene rings are oriented at a dihedral angle of 54.04 (3)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of two five-membered planar rings, which are oriented with respect to the adjacent benzene rings at dihedral angles of 2.66 (3) and 2.79 (3)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules. The water oxygen atom lies on a twofold rotation axis.
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spelling pubmed-29618302010-12-30 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate Chu, Qing-Yan Liu, Shan Liu, Yuan-Yuan Chen, Wei Zhu, Hong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the organic mol­ecule of the title compound, C(19)H(25)O(2)P·0.5H(2)O, the benzene rings are oriented at a dihedral angle of 54.04 (3)°. Intra­molecular C—H⋯O hydrogen bonds result in the formation of two five-membered planar rings, which are oriented with respect to the adjacent benzene rings at dihedral angles of 2.66 (3) and 2.79 (3)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules. The water oxygen atom lies on a twofold rotation axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961830/ /pubmed/21202868 http://dx.doi.org/10.1107/S1600536808016681 Text en © Chu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chu, Qing-Yan
Liu, Shan
Liu, Yuan-Yuan
Chen, Wei
Zhu, Hong-Jun
2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title_full 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title_fullStr 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title_full_unstemmed 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title_short 2-[Bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
title_sort 2-[bis(3,5-dimethyl­phen­yl)­phosphor­yl]­propan-2-ol hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961830/
https://www.ncbi.nlm.nih.gov/pubmed/21202868
http://dx.doi.org/10.1107/S1600536808016681
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