Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)

The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa­hedral geometry. The longest Fe—O and Fe—N bonds lie trans to each other...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961833/
https://www.ncbi.nlm.nih.gov/pubmed/21202804
http://dx.doi.org/10.1107/S1600536808018540
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author Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_facet Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_sort Hao, Lujiang
collection PubMed
description The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa­hedral geometry. The longest Fe—O and Fe—N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.
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spelling pubmed-29618332010-12-30 Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III) Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa­hedral geometry. The longest Fe—O and Fe—N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961833/ /pubmed/21202804 http://dx.doi.org/10.1107/S1600536808018540 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Mu, Chunhua
Kong, Binbin
Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title_full Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title_fullStr Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title_full_unstemmed Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title_short Tris[2-(propyl­imino­meth­yl)phenolato-κ(2) N,O]iron(III)
title_sort tris[2-(propyl­imino­meth­yl)phenolato-κ(2) n,o]iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961833/
https://www.ncbi.nlm.nih.gov/pubmed/21202804
http://dx.doi.org/10.1107/S1600536808018540
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AT muchunhua tris2propyliminomethylphenolatok2noironiii
AT kongbinbin tris2propyliminomethylphenolatok2noironiii

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