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Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)]
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methylquinoline ligands. The asymmetric unit contains one-half of the whole molecule, and there is an inversion center at the m...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961840/ https://www.ncbi.nlm.nih.gov/pubmed/21202752 http://dx.doi.org/10.1107/S1600536808016516 |
Sumario: | In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methylquinoline ligands. The asymmetric unit contains one-half of the whole molecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octahedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methylquinoline molecule [Cu—N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C—H⋯O as well as C—H⋯π and π–π interactions. |
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