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Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]

In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl­quinoline ligands. The asymmetric unit contains one-half of the whole mol­ecule, and there is an inversion center at the m...

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Detalles Bibliográficos
Autores principales: Yu, Seung Man, Park, Chi-Ho, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961840/
https://www.ncbi.nlm.nih.gov/pubmed/21202752
http://dx.doi.org/10.1107/S1600536808016516
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author Yu, Seung Man
Park, Chi-Ho
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Yu, Seung Man
Park, Chi-Ho
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Yu, Seung Man
collection PubMed
description In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl­quinoline ligands. The asymmetric unit contains one-half of the whole mol­ecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octa­hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methyl­quinoline mol­ecule [Cu—N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C—H⋯O as well as C—H⋯π and π–π interactions.
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spelling pubmed-29618402010-12-30 Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)] Yu, Seung Man Park, Chi-Ho Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl­quinoline ligands. The asymmetric unit contains one-half of the whole mol­ecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octa­hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methyl­quinoline mol­ecule [Cu—N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C—H⋯O as well as C—H⋯π and π–π interactions. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961840/ /pubmed/21202752 http://dx.doi.org/10.1107/S1600536808016516 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Seung Man
Park, Chi-Ho
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title_full Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title_fullStr Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title_full_unstemmed Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title_short Tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(II)]
title_sort tetra-μ-benzoato-bis­[(6-methyl­quino­line)­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961840/
https://www.ncbi.nlm.nih.gov/pubmed/21202752
http://dx.doi.org/10.1107/S1600536808016516
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