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Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)]
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methylquinoline ligands. The asymmetric unit contains one-half of the whole molecule, and there is an inversion center at the m...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961840/ https://www.ncbi.nlm.nih.gov/pubmed/21202752 http://dx.doi.org/10.1107/S1600536808016516 |
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author | Yu, Seung Man Park, Chi-Ho Kim, Pan-Gi Kim, Cheal Kim, Youngmee |
author_facet | Yu, Seung Man Park, Chi-Ho Kim, Pan-Gi Kim, Cheal Kim, Youngmee |
author_sort | Yu, Seung Man |
collection | PubMed |
description | In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methylquinoline ligands. The asymmetric unit contains one-half of the whole molecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octahedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methylquinoline molecule [Cu—N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C—H⋯O as well as C—H⋯π and π–π interactions. |
format | Text |
id | pubmed-2961840 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618402010-12-30 Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] Yu, Seung Man Park, Chi-Ho Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methylquinoline ligands. The asymmetric unit contains one-half of the whole molecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octahedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methylquinoline molecule [Cu—N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C—H⋯O as well as C—H⋯π and π–π interactions. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961840/ /pubmed/21202752 http://dx.doi.org/10.1107/S1600536808016516 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Seung Man Park, Chi-Ho Kim, Pan-Gi Kim, Cheal Kim, Youngmee Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title | Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title_full | Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title_fullStr | Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title_full_unstemmed | Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title_short | Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)] |
title_sort | tetra-μ-benzoato-bis[(6-methylquinoline)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961840/ https://www.ncbi.nlm.nih.gov/pubmed/21202752 http://dx.doi.org/10.1107/S1600536808016516 |
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