(1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene

X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C(10)H(12)Cl(2)O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloro­methyl­ene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structur...

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Detalles Bibliográficos
Autores principales: Tyrrell, Andrew J., Feast, George C., Robertson, Jeremy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961841/
https://www.ncbi.nlm.nih.gov/pubmed/21202895
http://dx.doi.org/10.1107/S1600536808017248
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author Tyrrell, Andrew J.
Feast, George C.
Robertson, Jeremy
author_facet Tyrrell, Andrew J.
Feast, George C.
Robertson, Jeremy
author_sort Tyrrell, Andrew J.
collection PubMed
description X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C(10)H(12)Cl(2)O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloro­methyl­ene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structure, mol­ecules pack to form sheets approximately perpendicular to the a and c axes.
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spelling pubmed-29618412010-12-30 (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene Tyrrell, Andrew J. Feast, George C. Robertson, Jeremy Acta Crystallogr Sect E Struct Rep Online Organic Papers X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C(10)H(12)Cl(2)O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloro­methyl­ene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structure, mol­ecules pack to form sheets approximately perpendicular to the a and c axes. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961841/ /pubmed/21202895 http://dx.doi.org/10.1107/S1600536808017248 Text en © Tyrrell et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tyrrell, Andrew J.
Feast, George C.
Robertson, Jeremy
(1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title_full (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title_fullStr (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title_full_unstemmed (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title_short (1RS,4SR)-3-Dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
title_sort (1rs,4sr)-3-dichloro­methyl­ene-1,4-dimethyl-2-oxabicyclo­[2.2.2]oct-5-ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961841/
https://www.ncbi.nlm.nih.gov/pubmed/21202895
http://dx.doi.org/10.1107/S1600536808017248
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AT robertsonjeremy 1rs4sr3dichloromethylene14dimethyl2oxabicyclo222oct5ene

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