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Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-diiron(III)-2-nickel(II)
The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is isostructural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coo...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961845/ https://www.ncbi.nlm.nih.gov/pubmed/21202781 http://dx.doi.org/10.1107/S1600536808017893 |
| _version_ | 1782189079831511040 |
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| author | Zhang, Xiutang Wei, Peihai Li, Bin |
| author_facet | Zhang, Xiutang Wei, Peihai Li, Bin |
| author_sort | Zhang, Xiutang |
| collection | PubMed |
| description | The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is isostructural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water molecule, forming a slightly distorted octahedral geometry. The two Fe(III) centres are bridged by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed via O—H⋯O and O—H⋯N hydrogen bonds. |
| format | Text |
| id | pubmed-2961845 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29618452010-12-30 Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-diiron(III)-2-nickel(II) Zhang, Xiutang Wei, Peihai Li, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is isostructural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water molecule, forming a slightly distorted octahedral geometry. The two Fe(III) centres are bridged by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed via O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961845/ /pubmed/21202781 http://dx.doi.org/10.1107/S1600536808017893 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Xiutang Wei, Peihai Li, Bin Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title | Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2)
N:C;2:3κ(2)
C:N-dicyanido-2κ(2)
C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
O,N,N′,O′;3κ(4)
O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title_full | Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2)
N:C;2:3κ(2)
C:N-dicyanido-2κ(2)
C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
O,N,N′,O′;3κ(4)
O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title_fullStr | Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2)
N:C;2:3κ(2)
C:N-dicyanido-2κ(2)
C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
O,N,N′,O′;3κ(4)
O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title_full_unstemmed | Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2)
N:C;2:3κ(2)
C:N-dicyanido-2κ(2)
C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
O,N,N′,O′;3κ(4)
O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title_short | Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2)
N:C;2:3κ(2)
C:N-dicyanido-2κ(2)
C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
O,N,N′,O′;3κ(4)
O,N,N′,O′-1,3-diiron(III)-2-nickel(II) |
| title_sort | diaqua-1κo,3κo-di-μ-cyanido-1:2κ(2)
n:c;2:3κ(2)
c:n-dicyanido-2κ(2)
c-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ(4)
o,n,n′,o′;3κ(4)
o,n,n′,o′-1,3-diiron(iii)-2-nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961845/ https://www.ncbi.nlm.nih.gov/pubmed/21202781 http://dx.doi.org/10.1107/S1600536808017893 |
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