Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate

The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[β-Mo(8)O(26)] (emim is 1-ethyl-3-methyl­imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [β-Mo(8)O(26)](4−) tetra­anion, which occupies a special positi...

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Detalles Bibliográficos
Autores principales: Lin, Shiwei, Chen, Weilin, Zhang, Zhiming, Liu, Wenli, Wang, Enbo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961847/
https://www.ncbi.nlm.nih.gov/pubmed/21202803
http://dx.doi.org/10.1107/S1600536808015936
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author Lin, Shiwei
Chen, Weilin
Zhang, Zhiming
Liu, Wenli
Wang, Enbo
author_facet Lin, Shiwei
Chen, Weilin
Zhang, Zhiming
Liu, Wenli
Wang, Enbo
author_sort Lin, Shiwei
collection PubMed
description The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[β-Mo(8)O(26)] (emim is 1-ethyl-3-methyl­imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [β-Mo(8)O(26)](4−) tetra­anion, which occupies a special position on an inversion centre. The β-[Mo(8)O(26)](4−) tetra­anion features eight distorted MoO(6) coordination octa­hedra linked together through bridging O atoms.
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spelling pubmed-29618472010-12-30 Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate Lin, Shiwei Chen, Weilin Zhang, Zhiming Liu, Wenli Wang, Enbo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[β-Mo(8)O(26)] (emim is 1-ethyl-3-methyl­imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [β-Mo(8)O(26)](4−) tetra­anion, which occupies a special position on an inversion centre. The β-[Mo(8)O(26)](4−) tetra­anion features eight distorted MoO(6) coordination octa­hedra linked together through bridging O atoms. International Union of Crystallography 2008-06-21 /pmc/articles/PMC2961847/ /pubmed/21202803 http://dx.doi.org/10.1107/S1600536808015936 Text en © Lin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Shiwei
Chen, Weilin
Zhang, Zhiming
Liu, Wenli
Wang, Enbo
Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title_full Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title_fullStr Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title_full_unstemmed Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title_short Tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
title_sort tetra­kis(1-ethyl-3-methyl­imidazolium) β-hexa­cosa­oxidoocta­molybdate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961847/
https://www.ncbi.nlm.nih.gov/pubmed/21202803
http://dx.doi.org/10.1107/S1600536808015936
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AT liuwenli tetrakis1ethyl3methylimidazoliumbhexacosaoxidooctamolybdate
AT wangenbo tetrakis1ethyl3methylimidazoliumbhexacosaoxidooctamolybdate

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