Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)

The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol­ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C—C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa­hedral configuration by two N atoms of the 4,4′...

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Autores principales: Hojjat Kashani, Leila, Amani, Vahid, Yousefi, Mohammad, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961848/
https://www.ncbi.nlm.nih.gov/pubmed/21202769
http://dx.doi.org/10.1107/S1600536808016796
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author Hojjat Kashani, Leila
Amani, Vahid
Yousefi, Mohammad
Khavasi, Hamid Reza
author_facet Hojjat Kashani, Leila
Amani, Vahid
Yousefi, Mohammad
Khavasi, Hamid Reza
author_sort Hojjat Kashani, Leila
collection PubMed
description The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol­ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C—C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa­hedral configuration by two N atoms of the 4,4′-dimethyl-2,2′-bipyridine ligand and four terminal Cl atoms. In the crystal structure, there are weak π–π inter­actions between pyridine rings, with a centroid–centroid distance of 4.365 (3) Å.
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spelling pubmed-29618482010-12-30 Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV) Hojjat Kashani, Leila Amani, Vahid Yousefi, Mohammad Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol­ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C—C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa­hedral configuration by two N atoms of the 4,4′-dimethyl-2,2′-bipyridine ligand and four terminal Cl atoms. In the crystal structure, there are weak π–π inter­actions between pyridine rings, with a centroid–centroid distance of 4.365 (3) Å. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961848/ /pubmed/21202769 http://dx.doi.org/10.1107/S1600536808016796 Text en © Hojjat Kashani et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hojjat Kashani, Leila
Amani, Vahid
Yousefi, Mohammad
Khavasi, Hamid Reza
Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title_full Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title_fullStr Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title_full_unstemmed Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title_short Tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)platinum(IV)
title_sort tetra­chlorido(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)platinum(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961848/
https://www.ncbi.nlm.nih.gov/pubmed/21202769
http://dx.doi.org/10.1107/S1600536808016796
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AT yousefimohammad tetrachlorido44dimethyl22bipyridinek2nnplatinumiv
AT khavasihamidreza tetrachlorido44dimethyl22bipyridinek2nnplatinumiv

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