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(3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid
The molecule of the title compound, C(20)H(32)O(4), is built up from three fused five-membered, six-membered and seven-membered rings. The five-membered ring has an envelope conformation, whereas the six- and seven-membered rings have chair conformations. The crystal structure is stabilized by stro...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961850/ https://www.ncbi.nlm.nih.gov/pubmed/21202969 http://dx.doi.org/10.1107/S1600536808018941 |
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| author | Brito, Iván Bórquez, Jorge Loyola, Luis Alberto Cárdenas, Alejandro López-Rodríguez, Matías |
| author_facet | Brito, Iván Bórquez, Jorge Loyola, Luis Alberto Cárdenas, Alejandro López-Rodríguez, Matías |
| author_sort | Brito, Iván |
| collection | PubMed |
| description | The molecule of the title compound, C(20)H(32)O(4), is built up from three fused five-membered, six-membered and seven-membered rings. The five-membered ring has an envelope conformation, whereas the six- and seven-membered rings have chair conformations. The crystal structure is stabilized by strong intermolecular O—H⋯O hydrogen bonds, forming a three-dimensional network. The absolute configuration was assigned on the basis of earlier chemical studies. |
| format | Text |
| id | pubmed-2961850 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29618502010-12-30 (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid Brito, Iván Bórquez, Jorge Loyola, Luis Alberto Cárdenas, Alejandro López-Rodríguez, Matías Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(20)H(32)O(4), is built up from three fused five-membered, six-membered and seven-membered rings. The five-membered ring has an envelope conformation, whereas the six- and seven-membered rings have chair conformations. The crystal structure is stabilized by strong intermolecular O—H⋯O hydrogen bonds, forming a three-dimensional network. The absolute configuration was assigned on the basis of earlier chemical studies. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961850/ /pubmed/21202969 http://dx.doi.org/10.1107/S1600536808018941 Text en © Brito et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Brito, Iván Bórquez, Jorge Loyola, Luis Alberto Cárdenas, Alejandro López-Rodríguez, Matías (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title | (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title_full | (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title_fullStr | (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title_full_unstemmed | (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title_short | (3S,3aS,5aS,7S,8S,10aS,10bR)-7,8-Dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylic acid |
| title_sort | (3s,3as,5as,7s,8s,10as,10br)-7,8-dihydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1h)-carboxylic acid |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961850/ https://www.ncbi.nlm.nih.gov/pubmed/21202969 http://dx.doi.org/10.1107/S1600536808018941 |
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