Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate

The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa­hedral coordination formed by four S atoms of two diethyl­dithio­carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features he...

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Detalles Bibliográficos
Autores principales: Boyd, Peter D. W., Rickard, Clifton E. F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961857/
https://www.ncbi.nlm.nih.gov/pubmed/21202776
http://dx.doi.org/10.1107/S160053680801725X
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author Boyd, Peter D. W.
Rickard, Clifton E. F.
author_facet Boyd, Peter D. W.
Rickard, Clifton E. F.
author_sort Boyd, Peter D. W.
collection PubMed
description The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa­hedral coordination formed by four S atoms of two diethyl­dithio­carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra­fluorido­borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C—H⋯F interactions.
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spelling pubmed-29618572010-12-30 Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate Boyd, Peter D. W. Rickard, Clifton E. F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa­hedral coordination formed by four S atoms of two diethyl­dithio­carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra­fluorido­borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C—H⋯F interactions. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961857/ /pubmed/21202776 http://dx.doi.org/10.1107/S160053680801725X Text en © Boyd and Rickard 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boyd, Peter D. W.
Rickard, Clifton E. F.
Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title_full Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title_fullStr Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title_full_unstemmed Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title_short Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate
title_sort bis(n,n-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(iii) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961857/
https://www.ncbi.nlm.nih.gov/pubmed/21202776
http://dx.doi.org/10.1107/S160053680801725X
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