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μ-Aqua-κ(2) O:O-di-μ-4-methylbenzoato-κ(4) O:O′-bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)nickel(II)]
In the title dinuclear complex, [Ni(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], each Ni(II) atom is six-coordinated by three carboxylate O atoms from three 4-methylbenzoate ligands, two N atoms from two 1,10-phenanthroline ligands, and one μ(2)-bridging aqua ligand. The dimeric complex is locate...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961858/ https://www.ncbi.nlm.nih.gov/pubmed/21202777 http://dx.doi.org/10.1107/S1600536808017285 |
Sumario: | In the title dinuclear complex, [Ni(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], each Ni(II) atom is six-coordinated by three carboxylate O atoms from three 4-methylbenzoate ligands, two N atoms from two 1,10-phenanthroline ligands, and one μ(2)-bridging aqua ligand. The dimeric complex is located on a crystallographic twofold axis and each Ni atom displays a distorted octahedral coordination geometry. The crystal structure is stabilized via intramolecular hydrogen bonding of the bridging water molecule and the uncoordinated carboxylate O atoms, and by C—H⋯O and π–π stacking interactions [centroid–centroid distances between neighbouring phenanthroline ring systems and between the benzene ring of a 4-methylbenzoate unit and a phenanthroline ring system are 3.662 (2) and 3.611 (3) Å, respectively]. |
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