S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate

In the title compound, C(8)H(11)N(2)S(+)·C(6)H(4)NO(5)S(−), the asymmetric unit is composed of two crystallographically independent S-benzyl­thio­uronium cations and two independent nitro­benzene­sulfonate anions. An intra­molecular hydrogen bond generates an S(5)S(5) ring motif. The crystal packing...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Razak, Ibrahim Abdul, Deepak D’Silva, E., Patil, P. S., Dharmaprakash, S. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961859/
https://www.ncbi.nlm.nih.gov/pubmed/21202837
http://dx.doi.org/10.1107/S1600536808016115
Descripción
Sumario:In the title compound, C(8)H(11)N(2)S(+)·C(6)H(4)NO(5)S(−), the asymmetric unit is composed of two crystallographically independent S-benzyl­thio­uronium cations and two independent nitro­benzene­sulfonate anions. An intra­molecular hydrogen bond generates an S(5)S(5) ring motif. The crystal packing is stabilized by intra­molecular C—H⋯O and inter­molecular C—H⋯O, N—H⋯O and N—H⋯S hydrogen bonds which, along with short S⋯O [3.034 (2) Å] and N⋯O [2.796 (3) Å] contacts, form a two-dimensional network parallel to the ab plane.

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