S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate

In the title compound, C(8)H(11)N(2)S(+)·C(6)H(4)NO(5)S(−), the asymmetric unit is composed of two crystallographically independent S-benzyl­thio­uronium cations and two independent nitro­benzene­sulfonate anions. An intra­molecular hydrogen bond generates an S(5)S(5) ring motif. The crystal packing...

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Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Razak, Ibrahim Abdul, Deepak D’Silva, E., Patil, P. S., Dharmaprakash, S. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961859/
https://www.ncbi.nlm.nih.gov/pubmed/21202837
http://dx.doi.org/10.1107/S1600536808016115
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Razak, Ibrahim Abdul
Deepak D’Silva, E.
Patil, P. S.
Dharmaprakash, S. M.
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Razak, Ibrahim Abdul
Deepak D’Silva, E.
Patil, P. S.
Dharmaprakash, S. M.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(8)H(11)N(2)S(+)·C(6)H(4)NO(5)S(−), the asymmetric unit is composed of two crystallographically independent S-benzyl­thio­uronium cations and two independent nitro­benzene­sulfonate anions. An intra­molecular hydrogen bond generates an S(5)S(5) ring motif. The crystal packing is stabilized by intra­molecular C—H⋯O and inter­molecular C—H⋯O, N—H⋯O and N—H⋯S hydrogen bonds which, along with short S⋯O [3.034 (2) Å] and N⋯O [2.796 (3) Å] contacts, form a two-dimensional network parallel to the ab plane.
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spelling pubmed-29618592010-12-30 S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate Fun, Hoong-Kun Jebas, Samuel Robinson Razak, Ibrahim Abdul Deepak D’Silva, E. Patil, P. S. Dharmaprakash, S. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(11)N(2)S(+)·C(6)H(4)NO(5)S(−), the asymmetric unit is composed of two crystallographically independent S-benzyl­thio­uronium cations and two independent nitro­benzene­sulfonate anions. An intra­molecular hydrogen bond generates an S(5)S(5) ring motif. The crystal packing is stabilized by intra­molecular C—H⋯O and inter­molecular C—H⋯O, N—H⋯O and N—H⋯S hydrogen bonds which, along with short S⋯O [3.034 (2) Å] and N⋯O [2.796 (3) Å] contacts, form a two-dimensional network parallel to the ab plane. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961859/ /pubmed/21202837 http://dx.doi.org/10.1107/S1600536808016115 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Razak, Ibrahim Abdul
Deepak D’Silva, E.
Patil, P. S.
Dharmaprakash, S. M.
S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title_full S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title_fullStr S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title_full_unstemmed S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title_short S-Benzyl­thio­uronium 3-nitro­benzene­sulfonate
title_sort s-benzyl­thio­uronium 3-nitro­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961859/
https://www.ncbi.nlm.nih.gov/pubmed/21202837
http://dx.doi.org/10.1107/S1600536808016115
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AT deepakdsilvae sbenzylthiouronium3nitrobenzenesulfonate
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AT dharmaprakashsm sbenzylthiouronium3nitrobenzenesulfonate

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