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Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethylformamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961861/ https://www.ncbi.nlm.nih.gov/pubmed/21202737 http://dx.doi.org/10.1107/S1600536808016267 |
Sumario: | In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethylformamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6) topology. The structure reveals trinuclear secondary building units and has an octahedral geometry at a central metal ion (occupying a [Image: see text] symmetry site) and tetrahedral geometries at two surrounding symmetrically equivalent metal ions lying on a threefold axis. The six-connected planar trinuclear Cd(II) centers, Cd(3)(O(2)CR)(6), play a role as potential nodes in generation of the relatively uncommon 3(6) topology. The coordinated DMF unit is disordered around the threefold axis. |
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