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Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology

In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethyl­formamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6...

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Detalles Bibliográficos
Autores principales: Lee, Dong-Heon, Park, Gyungse
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961861/
https://www.ncbi.nlm.nih.gov/pubmed/21202737
http://dx.doi.org/10.1107/S1600536808016267
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author Lee, Dong-Heon
Park, Gyungse
author_facet Lee, Dong-Heon
Park, Gyungse
author_sort Lee, Dong-Heon
collection PubMed
description In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethyl­formamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6) topology. The structure reveals trinuclear secondary building units and has an octa­hedral geometry at a central metal ion (occupying a [Image: see text] symmetry site) and tetra­hedral geometries at two surrounding symmetrically equivalent metal ions lying on a threefold axis. The six-connected planar trinuclear Cd(II) centers, Cd(3)(O(2)CR)(6), play a role as potential nodes in generation of the relatively uncommon 3(6) topology. The coordinated DMF unit is disordered around the threefold axis.
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spelling pubmed-29618612010-12-30 Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology Lee, Dong-Heon Park, Gyungse Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethyl­formamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6) topology. The structure reveals trinuclear secondary building units and has an octa­hedral geometry at a central metal ion (occupying a [Image: see text] symmetry site) and tetra­hedral geometries at two surrounding symmetrically equivalent metal ions lying on a threefold axis. The six-connected planar trinuclear Cd(II) centers, Cd(3)(O(2)CR)(6), play a role as potential nodes in generation of the relatively uncommon 3(6) topology. The coordinated DMF unit is disordered around the threefold axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961861/ /pubmed/21202737 http://dx.doi.org/10.1107/S1600536808016267 Text en © Lee and Park 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Dong-Heon
Park, Gyungse
Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title_full Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title_fullStr Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title_full_unstemmed Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title_short Poly[bis­(N,N-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
title_sort poly[bis­(n,n-dimethyl­formamide)tris­(μ(4)-trans-stilbene-4,4′-dicarboxyl­ato)­tricadmium(ii)]: a two-dimensional network with an unusual 3(6) topology
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961861/
https://www.ncbi.nlm.nih.gov/pubmed/21202737
http://dx.doi.org/10.1107/S1600536808016267
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