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Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology
In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethylformamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961861/ https://www.ncbi.nlm.nih.gov/pubmed/21202737 http://dx.doi.org/10.1107/S1600536808016267 |
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author | Lee, Dong-Heon Park, Gyungse |
author_facet | Lee, Dong-Heon Park, Gyungse |
author_sort | Lee, Dong-Heon |
collection | PubMed |
description | In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethylformamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6) topology. The structure reveals trinuclear secondary building units and has an octahedral geometry at a central metal ion (occupying a [Image: see text] symmetry site) and tetrahedral geometries at two surrounding symmetrically equivalent metal ions lying on a threefold axis. The six-connected planar trinuclear Cd(II) centers, Cd(3)(O(2)CR)(6), play a role as potential nodes in generation of the relatively uncommon 3(6) topology. The coordinated DMF unit is disordered around the threefold axis. |
format | Text |
id | pubmed-2961861 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618612010-12-30 Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology Lee, Dong-Heon Park, Gyungse Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(3)(C(16)H(10)O(4))(3)(C(3)H(7)NO)(2)](n) or [Cd(3)(SDA)(3)(DMF)(2)](n) (H(2)SDA is trans-stilbene-4,4′-dicarboxylic acid and DMF is dimethylformamide), the linear dicarboxylate ligand forms a two-dimensionally layered metal–organic network with the relatively uncommon 3(6) topology. The structure reveals trinuclear secondary building units and has an octahedral geometry at a central metal ion (occupying a [Image: see text] symmetry site) and tetrahedral geometries at two surrounding symmetrically equivalent metal ions lying on a threefold axis. The six-connected planar trinuclear Cd(II) centers, Cd(3)(O(2)CR)(6), play a role as potential nodes in generation of the relatively uncommon 3(6) topology. The coordinated DMF unit is disordered around the threefold axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961861/ /pubmed/21202737 http://dx.doi.org/10.1107/S1600536808016267 Text en © Lee and Park 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lee, Dong-Heon Park, Gyungse Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title | Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title_full | Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title_fullStr | Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title_full_unstemmed | Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title_short | Poly[bis(N,N-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(II)]: a two-dimensional network with an unusual 3(6) topology |
title_sort | poly[bis(n,n-dimethylformamide)tris(μ(4)-trans-stilbene-4,4′-dicarboxylato)tricadmium(ii)]: a two-dimensional network with an unusual 3(6) topology |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961861/ https://www.ncbi.nlm.nih.gov/pubmed/21202737 http://dx.doi.org/10.1107/S1600536808016267 |
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