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4,4′-[2,2-Dimethylpropane-1,3-diylbis(nitrilomethylidyne)]dibenzonitrile
The title compound, C(21)H(20)N(4), is a bidentate Schiff base ligand. An intramolecular C—H⋯N hydrogen bond forms a five-membered ring, producing an S(5) ring motif. The cyano and imino [–C(H(2))—N=C–] functional groups are coplanar with the benzene ring in each half of the molecule. The packing...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961864/ https://www.ncbi.nlm.nih.gov/pubmed/21202936 http://dx.doi.org/10.1107/S1600536808018345 |
Sumario: | The title compound, C(21)H(20)N(4), is a bidentate Schiff base ligand. An intramolecular C—H⋯N hydrogen bond forms a five-membered ring, producing an S(5) ring motif. The cyano and imino [–C(H(2))—N=C–] functional groups are coplanar with the benzene ring in each half of the molecule. The packing of the molecules is controlled by C—H⋯π and π–π interactions [centroid-to-centroid distance = 3.6944 (8) Å]. |
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