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4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile

The title compound, C(21)H(20)N(4), is a bidentate Schiff base ligand. An intra­molecular C—H⋯N hydrogen bond forms a five-membered ring, producing an S(5) ring motif. The cyano and imino [–C(H(2))—N=C–] functional groups are coplanar with the benzene ring in each half of the mol­ecule. The packing...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kargar, Hadi, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961864/
https://www.ncbi.nlm.nih.gov/pubmed/21202936
http://dx.doi.org/10.1107/S1600536808018345
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author Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_facet Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(21)H(20)N(4), is a bidentate Schiff base ligand. An intra­molecular C—H⋯N hydrogen bond forms a five-membered ring, producing an S(5) ring motif. The cyano and imino [–C(H(2))—N=C–] functional groups are coplanar with the benzene ring in each half of the mol­ecule. The packing of the mol­ecules is controlled by C—H⋯π and π–π inter­actions [centroid-to-centroid distance = 3.6944 (8) Å].
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spelling pubmed-29618642010-12-30 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile Fun, Hoong-Kun Kargar, Hadi Kia, Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(20)N(4), is a bidentate Schiff base ligand. An intra­molecular C—H⋯N hydrogen bond forms a five-membered ring, producing an S(5) ring motif. The cyano and imino [–C(H(2))—N=C–] functional groups are coplanar with the benzene ring in each half of the mol­ecule. The packing of the mol­ecules is controlled by C—H⋯π and π–π inter­actions [centroid-to-centroid distance = 3.6944 (8) Å]. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961864/ /pubmed/21202936 http://dx.doi.org/10.1107/S1600536808018345 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title_full 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title_fullStr 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title_full_unstemmed 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title_short 4,4′-[2,2-Dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
title_sort 4,4′-[2,2-dimethyl­propane-1,3-diyl­bis(nitrilo­methyl­idyne)]dibenzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961864/
https://www.ncbi.nlm.nih.gov/pubmed/21202936
http://dx.doi.org/10.1107/S1600536808018345
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