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Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate

The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclo­penta­dienyl ligand, two carbonyl ligands and a diphenyl­phosphine ligand in a...

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Detalles Bibliográficos
Autores principales: Shultz, Ginger V., Bossé, Stephanie A., Zakharov, Lev N., Tyler, David R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961865/
https://www.ncbi.nlm.nih.gov/pubmed/21202793
http://dx.doi.org/10.1107/S1600536808017996
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author Shultz, Ginger V.
Bossé, Stephanie A.
Zakharov, Lev N.
Tyler, David R.
author_facet Shultz, Ginger V.
Bossé, Stephanie A.
Zakharov, Lev N.
Tyler, David R.
author_sort Shultz, Ginger V.
collection PubMed
description The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclo­penta­dienyl ligand, two carbonyl ligands and a diphenyl­phosphine ligand in a piano-stool fashion.
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spelling pubmed-29618652010-12-30 Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate Shultz, Ginger V. Bossé, Stephanie A. Zakharov, Lev N. Tyler, David R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclo­penta­dienyl ligand, two carbonyl ligands and a diphenyl­phosphine ligand in a piano-stool fashion. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961865/ /pubmed/21202793 http://dx.doi.org/10.1107/S1600536808017996 Text en © Shultz et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shultz, Ginger V.
Bossé, Stephanie A.
Zakharov, Lev N.
Tyler, David R.
Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title_full Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title_fullStr Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title_full_unstemmed Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title_short Tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(Mo—Mo) hexane solvate
title_sort tetracarbon­ylbis(η(5)-cyclo­penta­dien­yl)bis(diphenyl­phosphine)dimolybdenum(mo—mo) hexane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961865/
https://www.ncbi.nlm.nih.gov/pubmed/21202793
http://dx.doi.org/10.1107/S1600536808017996
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