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Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate
The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclopentadienyl ligand, two carbonyl ligands and a diphenylphosphine ligand in a...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961865/ https://www.ncbi.nlm.nih.gov/pubmed/21202793 http://dx.doi.org/10.1107/S1600536808017996 |
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author | Shultz, Ginger V. Bossé, Stephanie A. Zakharov, Lev N. Tyler, David R. |
author_facet | Shultz, Ginger V. Bossé, Stephanie A. Zakharov, Lev N. Tyler, David R. |
author_sort | Shultz, Ginger V. |
collection | PubMed |
description | The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclopentadienyl ligand, two carbonyl ligands and a diphenylphosphine ligand in a piano-stool fashion. |
format | Text |
id | pubmed-2961865 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618652010-12-30 Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate Shultz, Ginger V. Bossé, Stephanie A. Zakharov, Lev N. Tyler, David R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclopentadienyl ligand, two carbonyl ligands and a diphenylphosphine ligand in a piano-stool fashion. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961865/ /pubmed/21202793 http://dx.doi.org/10.1107/S1600536808017996 Text en © Shultz et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shultz, Ginger V. Bossé, Stephanie A. Zakharov, Lev N. Tyler, David R. Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title | Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title_full | Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title_fullStr | Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title_full_unstemmed | Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title_short | Tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate |
title_sort | tetracarbonylbis(η(5)-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(mo—mo) hexane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961865/ https://www.ncbi.nlm.nih.gov/pubmed/21202793 http://dx.doi.org/10.1107/S1600536808017996 |
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