Diazido­bis(2,2′-biimidazole)manganese(II)

In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry [Image: see text]) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa­hedral MnN(6) geometry for the metal ion. In the crystal structure, N—H⋯N hydrogen bonds help...

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Detalles Bibliográficos
Autores principales: Zhang, Xiutang, Wei, Peihai, Li, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961868/
https://www.ncbi.nlm.nih.gov/pubmed/21202788
http://dx.doi.org/10.1107/S1600536808017984
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author Zhang, Xiutang
Wei, Peihai
Li, Bin
author_facet Zhang, Xiutang
Wei, Peihai
Li, Bin
author_sort Zhang, Xiutang
collection PubMed
description In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry [Image: see text]) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa­hedral MnN(6) geometry for the metal ion. In the crystal structure, N—H⋯N hydrogen bonds help to consolidate the packing.
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spelling pubmed-29618682010-12-30 Diazido­bis(2,2′-biimidazole)manganese(II) Zhang, Xiutang Wei, Peihai Li, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry [Image: see text]) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa­hedral MnN(6) geometry for the metal ion. In the crystal structure, N—H⋯N hydrogen bonds help to consolidate the packing. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961868/ /pubmed/21202788 http://dx.doi.org/10.1107/S1600536808017984 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiutang
Wei, Peihai
Li, Bin
Diazido­bis(2,2′-biimidazole)manganese(II)
title Diazido­bis(2,2′-biimidazole)manganese(II)
title_full Diazido­bis(2,2′-biimidazole)manganese(II)
title_fullStr Diazido­bis(2,2′-biimidazole)manganese(II)
title_full_unstemmed Diazido­bis(2,2′-biimidazole)manganese(II)
title_short Diazido­bis(2,2′-biimidazole)manganese(II)
title_sort diazido­bis(2,2′-biimidazole)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961868/
https://www.ncbi.nlm.nih.gov/pubmed/21202788
http://dx.doi.org/10.1107/S1600536808017984
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AT weipeihai diazidobis22biimidazolemanganeseii
AT libin diazidobis22biimidazolemanganeseii

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