A new polymorph of dimesitylborinic acid

A new polymorph of dimesitylborinic acid (or hydroxy­dimesitylborane), C(18)H(23)BO, showcasing different crystal packing and symmetry, complements the previously reported polymorph [Weese, Bartlett, Murray, Olmstead & Power (1987 ▶). Inorg. Chem. 26, 2409–2413; Entwistle, Batsanov & Marder...

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Detalles Bibliográficos
Autores principales: Kuhlmann, Matthias, Baumgartner, Thomas, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961869/
https://www.ncbi.nlm.nih.gov/pubmed/21202827
http://dx.doi.org/10.1107/S1600536808015638
Descripción
Sumario:A new polymorph of dimesitylborinic acid (or hydroxy­dimesitylborane), C(18)H(23)BO, showcasing different crystal packing and symmetry, complements the previously reported polymorph [Weese, Bartlett, Murray, Olmstead & Power (1987 ▶). Inorg. Chem. 26, 2409–2413; Entwistle, Batsanov & Marder (2007 ▶). Acta Cryst. E63, o2639–o2641]. The structure of the title compound contains only one mol­ecule in the asymmetric unit, and no O—H⋯O inter­actions are observed. However, mol­ecules are linked by weak inter­molecuar O—H⋯π(arene) inter­actions to form centrosymmetric dimers.

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