Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)

In the title complex, [Cu(C(3)H(4)N(2))(C(10)H(11)N(3))(2)](ClO(4))(2), the Cu(II) cation has a distorted trigonal-bipyramidal geometry defined by a CuN(2)N′(2)N′′ donor set. The imidazole ligand is disordered over two orientations of equal occupancy. Two of the perchlorate ion sites are located on...

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Detalles Bibliográficos
Autores principales: Liu, Chunyi, Zhou, Anyu, Wang, Songpei, Chen, Zhengping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961873/
https://www.ncbi.nlm.nih.gov/pubmed/21202774
http://dx.doi.org/10.1107/S1600536808017273
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author Liu, Chunyi
Zhou, Anyu
Wang, Songpei
Chen, Zhengping
author_facet Liu, Chunyi
Zhou, Anyu
Wang, Songpei
Chen, Zhengping
author_sort Liu, Chunyi
collection PubMed
description In the title complex, [Cu(C(3)H(4)N(2))(C(10)H(11)N(3))(2)](ClO(4))(2), the Cu(II) cation has a distorted trigonal-bipyramidal geometry defined by a CuN(2)N′(2)N′′ donor set. The imidazole ligand is disordered over two orientations of equal occupancy. Two of the perchlorate ion sites are located on a twofold rotation axis, and one of is disordered over two sites of equal occupancy. In the crystal structure there is a two-dimensional infinite network of hydrogen-bonded mol­ecules parallel to the ab plane.
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spelling pubmed-29618732010-12-30 Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate) Liu, Chunyi Zhou, Anyu Wang, Songpei Chen, Zhengping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(3)H(4)N(2))(C(10)H(11)N(3))(2)](ClO(4))(2), the Cu(II) cation has a distorted trigonal-bipyramidal geometry defined by a CuN(2)N′(2)N′′ donor set. The imidazole ligand is disordered over two orientations of equal occupancy. Two of the perchlorate ion sites are located on a twofold rotation axis, and one of is disordered over two sites of equal occupancy. In the crystal structure there is a two-dimensional infinite network of hydrogen-bonded mol­ecules parallel to the ab plane. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961873/ /pubmed/21202774 http://dx.doi.org/10.1107/S1600536808017273 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Chunyi
Zhou, Anyu
Wang, Songpei
Chen, Zhengping
Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title_full Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title_fullStr Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title_full_unstemmed Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title_short Bis[4,5-dimethyl-2-(2-pyrid­yl)-1H-imidazole-κ(2) N (2),N (3)](1H-imidazole-κN (3))copper(II) bis­(perchlorate)
title_sort bis[4,5-dimethyl-2-(2-pyrid­yl)-1h-imidazole-κ(2) n (2),n (3)](1h-imidazole-κn (3))copper(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961873/
https://www.ncbi.nlm.nih.gov/pubmed/21202774
http://dx.doi.org/10.1107/S1600536808017273
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AT wangsongpei bis45dimethyl22pyridyl1himidazolek2n2n31himidazolekn3copperiibisperchlorate
AT chenzhengping bis45dimethyl22pyridyl1himidazolek2n2n31himidazolekn3copperiibisperchlorate

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