Cargando…

Poly[[diaqua­tris[μ(4)-(p-phenyl­enedi­oxy)diacetato]didysprosium(III)] dihydrate]

The title dysprosium coordination polymer, {[Dy(2)(C(10)H(8)O(6))(3)(H(2)O)(2)]·2H(2)O}(n), was synthesized by reacting dysprosium(III) nitrate and the flexible ligand (p-phenyl­enedi­oxy)diacetic acid under hydro­thermal conditions. Each Dy(III) ion is coordinated by nine O atoms in a tricapped tri...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Wang, Dao-Wu, Wang, Yuan-Rui, Zhang, Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961875/
https://www.ncbi.nlm.nih.gov/pubmed/21202796
http://dx.doi.org/10.1107/S1600536808017649
Descripción
Sumario:The title dysprosium coordination polymer, {[Dy(2)(C(10)H(8)O(6))(3)(H(2)O)(2)]·2H(2)O}(n), was synthesized by reacting dysprosium(III) nitrate and the flexible ligand (p-phenyl­enedi­oxy)diacetic acid under hydro­thermal conditions. Each Dy(III) ion is coordinated by nine O atoms in a tricapped trigonal prismatic geometry. The DyO(9) polyhedra form layers parallel to the bc plane. The rigid benzene rings of the anions link the layers along the a axis, forming a three-dimensional framework.