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Poly[[diaquatris[μ(4)-(p-phenylenedioxy)diacetato]didysprosium(III)] dihydrate]
The title dysprosium coordination polymer, {[Dy(2)(C(10)H(8)O(6))(3)(H(2)O)(2)]·2H(2)O}(n), was synthesized by reacting dysprosium(III) nitrate and the flexible ligand (p-phenylenedioxy)diacetic acid under hydrothermal conditions. Each Dy(III) ion is coordinated by nine O atoms in a tricapped tri...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961875/ https://www.ncbi.nlm.nih.gov/pubmed/21202796 http://dx.doi.org/10.1107/S1600536808017649 |
Sumario: | The title dysprosium coordination polymer, {[Dy(2)(C(10)H(8)O(6))(3)(H(2)O)(2)]·2H(2)O}(n), was synthesized by reacting dysprosium(III) nitrate and the flexible ligand (p-phenylenedioxy)diacetic acid under hydrothermal conditions. Each Dy(III) ion is coordinated by nine O atoms in a tricapped trigonal prismatic geometry. The DyO(9) polyhedra form layers parallel to the bc plane. The rigid benzene rings of the anions link the layers along the a axis, forming a three-dimensional framework. |
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