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Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]

The title compound, [Dy(2)(C(3)H(2)O(4))(3)(H(2)O)(6)](n), forms a coordination polymeric structure comprising hydrated dysprosium ions and malonate ligands. In the asymmetric unit, there are one dysprosium ion, one and a half malonate ligands, and three water mol­ecules. Each Dy(III) atom is coordi...

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Detalles Bibliográficos
Autores principales: Fang, Zhan-Qiang, Zeng, Rong-Hua, Song, Zhao-Feng, Yang, Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961881/
https://www.ncbi.nlm.nih.gov/pubmed/21202748
http://dx.doi.org/10.1107/S1600536808015961
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author Fang, Zhan-Qiang
Zeng, Rong-Hua
Song, Zhao-Feng
Yang, Mei
author_facet Fang, Zhan-Qiang
Zeng, Rong-Hua
Song, Zhao-Feng
Yang, Mei
author_sort Fang, Zhan-Qiang
collection PubMed
description The title compound, [Dy(2)(C(3)H(2)O(4))(3)(H(2)O)(6)](n), forms a coordination polymeric structure comprising hydrated dysprosium ions and malonate ligands. In the asymmetric unit, there are one dysprosium ion, one and a half malonate ligands, and three water mol­ecules. Each Dy(III) atom is coordinated by six O atoms from four malonate ligands and by three water mol­ecules, and displays a tricapped trigonal–prismatic coordination geometry. The malonate ligands adopt two types of coordination mode, linking dysprosium centres to form a three-dimensional coordination polymer. The extensive network of hydrogen bonds in this polymer enhances the structural stability.
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spelling pubmed-29618812010-12-30 Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)] Fang, Zhan-Qiang Zeng, Rong-Hua Song, Zhao-Feng Yang, Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Dy(2)(C(3)H(2)O(4))(3)(H(2)O)(6)](n), forms a coordination polymeric structure comprising hydrated dysprosium ions and malonate ligands. In the asymmetric unit, there are one dysprosium ion, one and a half malonate ligands, and three water mol­ecules. Each Dy(III) atom is coordinated by six O atoms from four malonate ligands and by three water mol­ecules, and displays a tricapped trigonal–prismatic coordination geometry. The malonate ligands adopt two types of coordination mode, linking dysprosium centres to form a three-dimensional coordination polymer. The extensive network of hydrogen bonds in this polymer enhances the structural stability. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961881/ /pubmed/21202748 http://dx.doi.org/10.1107/S1600536808015961 Text en © Fang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fang, Zhan-Qiang
Zeng, Rong-Hua
Song, Zhao-Feng
Yang, Mei
Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title_full Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title_fullStr Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title_full_unstemmed Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title_short Poly[hexa­aqua­tri-μ-malonato-didysprosium(III)]
title_sort poly[hexa­aqua­tri-μ-malonato-didysprosium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961881/
https://www.ncbi.nlm.nih.gov/pubmed/21202748
http://dx.doi.org/10.1107/S1600536808015961
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