2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol

The two mol­ecules of the title compound, C(13)H(8)BrClFNO, in the asymmetric unit are inter­connected by π–π inter­actions between the salicylaldehyde and aniline units, the shortest inter­planar distance being 3.317 (3) Å. These pairs and their translation equivalents are further linked by C—H⋯F h...

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Detalles Bibliográficos
Autores principales: Puthilibai, G., Vasudhevan, S., Rajagopal, G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961884/
https://www.ncbi.nlm.nih.gov/pubmed/21202957
http://dx.doi.org/10.1107/S1600536808017443
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author Puthilibai, G.
Vasudhevan, S.
Rajagopal, G.
author_facet Puthilibai, G.
Vasudhevan, S.
Rajagopal, G.
author_sort Puthilibai, G.
collection PubMed
description The two mol­ecules of the title compound, C(13)H(8)BrClFNO, in the asymmetric unit are inter­connected by π–π inter­actions between the salicylaldehyde and aniline units, the shortest inter­planar distance being 3.317 (3) Å. These pairs and their translation equivalents are further linked by C—H⋯F hydrogen bonds, forming a one-dimensional infinite chain. In addition, there is an intra­molecular O—H⋯N hydrogen bond connecting the OH group and the imine N atom.
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spelling pubmed-29618842010-12-30 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol Puthilibai, G. Vasudhevan, S. Rajagopal, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The two mol­ecules of the title compound, C(13)H(8)BrClFNO, in the asymmetric unit are inter­connected by π–π inter­actions between the salicylaldehyde and aniline units, the shortest inter­planar distance being 3.317 (3) Å. These pairs and their translation equivalents are further linked by C—H⋯F hydrogen bonds, forming a one-dimensional infinite chain. In addition, there is an intra­molecular O—H⋯N hydrogen bond connecting the OH group and the imine N atom. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961884/ /pubmed/21202957 http://dx.doi.org/10.1107/S1600536808017443 Text en © Puthilibai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Puthilibai, G.
Vasudhevan, S.
Rajagopal, G.
2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title_full 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title_fullStr 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title_full_unstemmed 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title_short 2-Bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
title_sort 2-bromo-4-chloro-6-(4-fluoro­phenyl­imino­meth­yl)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961884/
https://www.ncbi.nlm.nih.gov/pubmed/21202957
http://dx.doi.org/10.1107/S1600536808017443
work_keys_str_mv AT puthilibaig 2bromo4chloro64fluorophenyliminomethylphenol
AT vasudhevans 2bromo4chloro64fluorophenyliminomethylphenol
AT rajagopalg 2bromo4chloro64fluorophenyliminomethylphenol

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