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(E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate
In the title compound, C(9)H(10)N(2)O(3), the hydroxy group and the C=N—N unit are coplanar with the benzene ring. The benzene rings of inversion-related molecules are stacked with their centroids separated by a distance of 3.7703 (9) Å, indicating weak π–π interactions. In the crystal structure,...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961885/ https://www.ncbi.nlm.nih.gov/pubmed/21202931 http://dx.doi.org/10.1107/S1600536808018096 |
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author | Cheng, Xiang-Wei |
author_facet | Cheng, Xiang-Wei |
author_sort | Cheng, Xiang-Wei |
collection | PubMed |
description | In the title compound, C(9)H(10)N(2)O(3), the hydroxy group and the C=N—N unit are coplanar with the benzene ring. The benzene rings of inversion-related molecules are stacked with their centroids separated by a distance of 3.7703 (9) Å, indicating weak π–π interactions. In the crystal structure, C—H⋯O, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link molecules into a infinite two-dimensional network along the a axis. |
format | Text |
id | pubmed-2961885 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618852010-12-30 (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate Cheng, Xiang-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)N(2)O(3), the hydroxy group and the C=N—N unit are coplanar with the benzene ring. The benzene rings of inversion-related molecules are stacked with their centroids separated by a distance of 3.7703 (9) Å, indicating weak π–π interactions. In the crystal structure, C—H⋯O, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link molecules into a infinite two-dimensional network along the a axis. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961885/ /pubmed/21202931 http://dx.doi.org/10.1107/S1600536808018096 Text en © Xiang-Wei Cheng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Cheng, Xiang-Wei (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title | (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title_full | (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title_fullStr | (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title_full_unstemmed | (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title_short | (E)-Methyl N′-(4-hydroxybenzylidene)hydrazinecarboxylate |
title_sort | (e)-methyl n′-(4-hydroxybenzylidene)hydrazinecarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961885/ https://www.ncbi.nlm.nih.gov/pubmed/21202931 http://dx.doi.org/10.1107/S1600536808018096 |
work_keys_str_mv | AT chengxiangwei emethyln4hydroxybenzylidenehydrazinecarboxylate |