(S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one

The title compound, C(21)H(26)N(2)O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxamide from (S)-2-benzyl­amino-N-tert-butyl-3-phenyl­propanamide and dimethoxy­methane. The mol­ecules are linked by weak C—H⋯O h...

Descripción completa

Detalles Bibliográficos
Autores principales: Zheng, Jian-Feng, Guo, Jian-Nan, Huang, Su-Yu, Teng, Bo, Jin, Li-Ren
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961886/
https://www.ncbi.nlm.nih.gov/pubmed/21202954
http://dx.doi.org/10.1107/S1600536808018461
_version_ 1782189089558102016
author Zheng, Jian-Feng
Guo, Jian-Nan
Huang, Su-Yu
Teng, Bo
Jin, Li-Ren
author_facet Zheng, Jian-Feng
Guo, Jian-Nan
Huang, Su-Yu
Teng, Bo
Jin, Li-Ren
author_sort Zheng, Jian-Feng
collection PubMed
description The title compound, C(21)H(26)N(2)O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxamide from (S)-2-benzyl­amino-N-tert-butyl-3-phenyl­propanamide and dimethoxy­methane. The mol­ecules are linked by weak C—H⋯O hydrogen bonds, generating linear chains parallel to the b axis. C—H⋯π inter­actions provide further stability for the crystal structure. The planes of the two phenyl rings make a dihedral angle of 84.1 (1)°. The absolute configuration was known from the starting material.
format Text
id pubmed-2961886
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29618862010-12-30 (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one Zheng, Jian-Feng Guo, Jian-Nan Huang, Su-Yu Teng, Bo Jin, Li-Ren Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(26)N(2)O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxamide from (S)-2-benzyl­amino-N-tert-butyl-3-phenyl­propanamide and dimethoxy­methane. The mol­ecules are linked by weak C—H⋯O hydrogen bonds, generating linear chains parallel to the b axis. C—H⋯π inter­actions provide further stability for the crystal structure. The planes of the two phenyl rings make a dihedral angle of 84.1 (1)°. The absolute configuration was known from the starting material. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961886/ /pubmed/21202954 http://dx.doi.org/10.1107/S1600536808018461 Text en © Zheng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Jian-Feng
Guo, Jian-Nan
Huang, Su-Yu
Teng, Bo
Jin, Li-Ren
(S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title_full (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title_fullStr (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title_full_unstemmed (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title_short (S)-1,5-Dibenzyl-3-tert-butyl­imidazol­idin-4-one
title_sort (s)-1,5-dibenzyl-3-tert-butyl­imidazol­idin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961886/
https://www.ncbi.nlm.nih.gov/pubmed/21202954
http://dx.doi.org/10.1107/S1600536808018461
work_keys_str_mv AT zhengjianfeng s15dibenzyl3tertbutylimidazolidin4one
AT guojiannan s15dibenzyl3tertbutylimidazolidin4one
AT huangsuyu s15dibenzyl3tertbutylimidazolidin4one
AT tengbo s15dibenzyl3tertbutylimidazolidin4one
AT jinliren s15dibenzyl3tertbutylimidazolidin4one

Ejemplares similares