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Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)

The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) and one 1-amino-4-methyl­pyridinium cation. The Ni(II) atom is located on an inversion centre. In...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Lan, Yao, Bing-Qian, Zhang, Shao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961888/
https://www.ncbi.nlm.nih.gov/pubmed/21202816
http://dx.doi.org/10.1107/S1600536808018886
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author Liu, Jian-Lan
Yao, Bing-Qian
Zhang, Shao-Ming
author_facet Liu, Jian-Lan
Yao, Bing-Qian
Zhang, Shao-Ming
author_sort Liu, Jian-Lan
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) and one 1-amino-4-methyl­pyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules.
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spelling pubmed-29618882010-12-30 Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II) Liu, Jian-Lan Yao, Bing-Qian Zhang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) and one 1-amino-4-methyl­pyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961888/ /pubmed/21202816 http://dx.doi.org/10.1107/S1600536808018886 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jian-Lan
Yao, Bing-Qian
Zhang, Shao-Ming
Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_full Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_fullStr Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_full_unstemmed Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_short Bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_sort bis(1-amino-4-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) s,s′)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961888/
https://www.ncbi.nlm.nih.gov/pubmed/21202816
http://dx.doi.org/10.1107/S1600536808018886
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AT zhangshaoming bis1amino4methylpyridiniumbis12dicyanoethene12dithiolatok2ssnickelateii