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Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2) S,S′)nickelate(II)
The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitriledithiolate or 1,2-dicyanoethene-1,2-dithiolate) and one 1-amino-4-methylpyridinium cation. The Ni(II) atom is located on an inversion centre. In...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961888/ https://www.ncbi.nlm.nih.gov/pubmed/21202816 http://dx.doi.org/10.1107/S1600536808018886 |
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author | Liu, Jian-Lan Yao, Bing-Qian Zhang, Shao-Ming |
author_facet | Liu, Jian-Lan Yao, Bing-Qian Zhang, Shao-Ming |
author_sort | Liu, Jian-Lan |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitriledithiolate or 1,2-dicyanoethene-1,2-dithiolate) and one 1-amino-4-methylpyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link the molecules. |
format | Text |
id | pubmed-2961888 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618882010-12-30 Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2) S,S′)nickelate(II) Liu, Jian-Lan Yao, Bing-Qian Zhang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2−) anion (mnt is maleonitriledithiolate or 1,2-dicyanoethene-1,2-dithiolate) and one 1-amino-4-methylpyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link the molecules. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961888/ /pubmed/21202816 http://dx.doi.org/10.1107/S1600536808018886 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jian-Lan Yao, Bing-Qian Zhang, Shao-Ming Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2) S,S′)nickelate(II) |
title | Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
S,S′)nickelate(II) |
title_full | Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
S,S′)nickelate(II) |
title_fullStr | Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
S,S′)nickelate(II) |
title_full_unstemmed | Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
S,S′)nickelate(II) |
title_short | Bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
S,S′)nickelate(II) |
title_sort | bis(1-amino-4-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2)
s,s′)nickelate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961888/ https://www.ncbi.nlm.nih.gov/pubmed/21202816 http://dx.doi.org/10.1107/S1600536808018886 |
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