2-(2-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O,N,O′)aluminate(III) trihydrate

The title compound, (C(10)H(9)N(2))[Al(C(7)H(3)NO(4))(2)]·3H(2)O or (2,2′-bipyH)[Al(pydc)(2)]·3H(2)O (where 2,2′-bipy is 2,2′-bipyridine and pydcH(2) is pyridine-2,6-dicarboxylic acid), was synthesized by the reaction of aluminium(III) nitrate nona­hydrate with pyridine-2,6-dicarboxylic acid and 2,2′-bipyridine in a 1:2:4 molar ratio in aqueous solution. This compound is composed of an anionic complex, [Al(pydc)(2)](−), a protonated 2,2′-bipyridine mol­ecule as a counter-ion, (2,2′-bipyH)(+), and three uncoordinated water mol­ecules. The anion is a six-coordinate complex, with the Al(III) atom in a distorted octa­hedral geometry coordinated by two tridentate pyridine-2,6-dicarboxyl­ate groups. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds, π–π stacking between two aromatic rings [centroid–centroid distance = 3.827 (10) Å], and C=O⋯π stacking [with distances of 3.2311 (13), 3.4924 (14) and 3.5731 (13) Å], connect the various components to form a supra­molecular structure.