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{(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II)
The title compound, [ZnCl(2)(C(12)H(16)BrClN(2)O)], is a mononuclear zinc(II) complex. The Zn(II) atom is four-coordinate in a tetrahedral geometry, binding to the phenolate O and imine N atoms of the zwitterionic Schiff base ligand and to two Cl(−) ions. In the crystal structure, molecules are li...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961892/ https://www.ncbi.nlm.nih.gov/pubmed/21202743 http://dx.doi.org/10.1107/S1600536808016255 |
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author | Ye, Li-Juan You, Zhonglu |
author_facet | Ye, Li-Juan You, Zhonglu |
author_sort | Ye, Li-Juan |
collection | PubMed |
description | The title compound, [ZnCl(2)(C(12)H(16)BrClN(2)O)], is a mononuclear zinc(II) complex. The Zn(II) atom is four-coordinate in a tetrahedral geometry, binding to the phenolate O and imine N atoms of the zwitterionic Schiff base ligand and to two Cl(−) ions. In the crystal structure, molecules are linked through intermolecular N—H⋯Cl hydrogen bonds to form chains running along the a axis. |
format | Text |
id | pubmed-2961892 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618922010-12-30 {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) Ye, Li-Juan You, Zhonglu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnCl(2)(C(12)H(16)BrClN(2)O)], is a mononuclear zinc(II) complex. The Zn(II) atom is four-coordinate in a tetrahedral geometry, binding to the phenolate O and imine N atoms of the zwitterionic Schiff base ligand and to two Cl(−) ions. In the crystal structure, molecules are linked through intermolecular N—H⋯Cl hydrogen bonds to form chains running along the a axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961892/ /pubmed/21202743 http://dx.doi.org/10.1107/S1600536808016255 Text en © Ye and You 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ye, Li-Juan You, Zhonglu {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title | {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title_full | {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title_fullStr | {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title_full_unstemmed | {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title_short | {(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II) |
title_sort | {(e)-2-bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961892/ https://www.ncbi.nlm.nih.gov/pubmed/21202743 http://dx.doi.org/10.1107/S1600536808016255 |
work_keys_str_mv | AT yelijuan e2bromo4chloro63dimethylammoniopropyliminomethylphenolatodichloridozincii AT youzhonglu e2bromo4chloro63dimethylammoniopropyliminomethylphenolatodichloridozincii |