Chlorido(dimethyl sulfoxide)(pyridine-2-thiol­ato N-oxide-κ(2) S,O)platinum(II)

The asymmetric unit of the title compound, [Pt(C(5)H(4)NOS)Cl(C(2)H(6)OS)], contains two independent complex mol­ecules having similar geometries. Each Pt(II) atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl su...

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Detalles Bibliográficos
Autores principales: Ravindran Durai Nayagam, B., Jebas, Samuel Robinson, Selvarathy Grace, P., Schollmeyer, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961893/
https://www.ncbi.nlm.nih.gov/pubmed/21202820
http://dx.doi.org/10.1107/S1600536808019041
Descripción
Sumario:The asymmetric unit of the title compound, [Pt(C(5)H(4)NOS)Cl(C(2)H(6)OS)], contains two independent complex mol­ecules having similar geometries. Each Pt(II) atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide mol­ecule and one terminal Cl(−) ion. The mol­ecules are linked into a three-dimensional framework by C—H⋯O and C—H⋯Cl hydrogen bonds.

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