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6-Methyl-2,4-diphenylquinoline
The molecules of the title compound, C(22)H(17)N, are linked by weak interactions, among which the most prominent are C—H⋯π interactions. The dihedral angles between the phenyl rings and the quinoline ring system are 43.3 (3) and 21.4 (3)°. The title product resulted from a three-component reacti...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961894/ https://www.ncbi.nlm.nih.gov/pubmed/21202829 http://dx.doi.org/10.1107/S1600536808015651 |
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author | Huo, Xing Xu, Yanfen Li, Xinyun Pan, Xinfu |
author_facet | Huo, Xing Xu, Yanfen Li, Xinyun Pan, Xinfu |
author_sort | Huo, Xing |
collection | PubMed |
description | The molecules of the title compound, C(22)H(17)N, are linked by weak interactions, among which the most prominent are C—H⋯π interactions. The dihedral angles between the phenyl rings and the quinoline ring system are 43.3 (3) and 21.4 (3)°. The title product resulted from a three-component reaction of benzaldehyde, 1-ethynylbenzene and p-toluidine via C—H activation of 1-ethynylbenzene catalyzed by CuI in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. |
format | Text |
id | pubmed-2961894 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618942010-12-30 6-Methyl-2,4-diphenylquinoline Huo, Xing Xu, Yanfen Li, Xinyun Pan, Xinfu Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecules of the title compound, C(22)H(17)N, are linked by weak interactions, among which the most prominent are C—H⋯π interactions. The dihedral angles between the phenyl rings and the quinoline ring system are 43.3 (3) and 21.4 (3)°. The title product resulted from a three-component reaction of benzaldehyde, 1-ethynylbenzene and p-toluidine via C—H activation of 1-ethynylbenzene catalyzed by CuI in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961894/ /pubmed/21202829 http://dx.doi.org/10.1107/S1600536808015651 Text en © Huo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Huo, Xing Xu, Yanfen Li, Xinyun Pan, Xinfu 6-Methyl-2,4-diphenylquinoline |
title | 6-Methyl-2,4-diphenylquinoline |
title_full | 6-Methyl-2,4-diphenylquinoline |
title_fullStr | 6-Methyl-2,4-diphenylquinoline |
title_full_unstemmed | 6-Methyl-2,4-diphenylquinoline |
title_short | 6-Methyl-2,4-diphenylquinoline |
title_sort | 6-methyl-2,4-diphenylquinoline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961894/ https://www.ncbi.nlm.nih.gov/pubmed/21202829 http://dx.doi.org/10.1107/S1600536808015651 |
work_keys_str_mv | AT huoxing 6methyl24diphenylquinoline AT xuyanfen 6methyl24diphenylquinoline AT lixinyun 6methyl24diphenylquinoline AT panxinfu 6methyl24diphenylquinoline |