catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]

The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa­hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric c...

Descripción completa

Detalles Bibliográficos
Autores principales: Berdugo, Erick, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961896/
https://www.ncbi.nlm.nih.gov/pubmed/21202772
http://dx.doi.org/10.1107/S1600536808017121
Descripción
Sumario:The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa­hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis­(4-pyridylmethyl­ene)hydrazine4-pyridine mol­ecule is also disposed about a centre of inversion. One isobutoxy group is disordered equally over two positions.

Ejemplares similares