catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]

The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa­hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric c...

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Detalles Bibliográficos
Autores principales: Berdugo, Erick, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961896/
https://www.ncbi.nlm.nih.gov/pubmed/21202772
http://dx.doi.org/10.1107/S1600536808017121
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author Berdugo, Erick
Tiekink, Edward R. T.
author_facet Berdugo, Erick
Tiekink, Edward R. T.
author_sort Berdugo, Erick
collection PubMed
description The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa­hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis­(4-pyridylmethyl­ene)hydrazine4-pyridine mol­ecule is also disposed about a centre of inversion. One isobutoxy group is disordered equally over two positions.
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spelling pubmed-29618962010-12-30 catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate] Berdugo, Erick Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa­hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis­(4-pyridylmethyl­ene)hydrazine4-pyridine mol­ecule is also disposed about a centre of inversion. One isobutoxy group is disordered equally over two positions. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961896/ /pubmed/21202772 http://dx.doi.org/10.1107/S1600536808017121 Text en © Berdugo and Tiekink 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Berdugo, Erick
Tiekink, Edward R. T.
catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title_full catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title_fullStr catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title_full_unstemmed catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title_short catena-Poly[[[bis­(O,O′-diisobutyl dithio­phosphato-κ(2) S,S′)nickel(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) N:N′] toluene disolvate]
title_sort catena-poly[[[bis­(o,o′-diisobutyl dithio­phosphato-κ(2) s,s′)nickel(ii)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ(2) n:n′] toluene disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961896/
https://www.ncbi.nlm.nih.gov/pubmed/21202772
http://dx.doi.org/10.1107/S1600536808017121
work_keys_str_mv AT berdugoerick catenapolybisoodiisobutyldithiophosphatok2ssnickeliim12bis4pyridylmethylenehydrazinek2nntoluenedisolvate
AT tiekinkedwardrt catenapolybisoodiisobutyldithiophosphatok2ssnickeliim12bis4pyridylmethylenehydrazinek2nntoluenedisolvate

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