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Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)

In the title compound, [CoCl(2)(C(12)H(14)ClN(3))(2)], the central Co(II) ion lies on a twofold rotation axis and adopts a distorted tetra­hedral coordination geometry defined by two N atoms from two 2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole ligands and two chloride anions....

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Zhao, Yao, Geng, Zhi-Rong, Wang, Zhi-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961898/
https://www.ncbi.nlm.nih.gov/pubmed/21202795
http://dx.doi.org/10.1107/S1600536808018011
Descripción
Sumario:In the title compound, [CoCl(2)(C(12)H(14)ClN(3))(2)], the central Co(II) ion lies on a twofold rotation axis and adopts a distorted tetra­hedral coordination geometry defined by two N atoms from two 2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole ligands and two chloride anions. The Cl atom located in the side chain of the ligand is involved in inter­molecular C—H⋯Cl hydrogen bonding, which links neutral complex units into a one-dimensional right-handed helical chain running along a crystallographic 4(1) axis. Such hydrogen-bonded helical chains are connected to each other to form a homochiral three-dimensional supra­molecular network. One C atom of the 2-chloro­ethyl chain is disordered over two positions, with site-occupancy factors of 0.52 and 0.48.