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Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)

In the title compound, [CoCl(2)(C(12)H(14)ClN(3))(2)], the central Co(II) ion lies on a twofold rotation axis and adopts a distorted tetra­hedral coordination geometry defined by two N atoms from two 2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole ligands and two chloride anions....

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Zhao, Yao, Geng, Zhi-Rong, Wang, Zhi-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961898/
https://www.ncbi.nlm.nih.gov/pubmed/21202795
http://dx.doi.org/10.1107/S1600536808018011
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author Zhang, Zhong
Zhao, Yao
Geng, Zhi-Rong
Wang, Zhi-Lin
author_facet Zhang, Zhong
Zhao, Yao
Geng, Zhi-Rong
Wang, Zhi-Lin
author_sort Zhang, Zhong
collection PubMed
description In the title compound, [CoCl(2)(C(12)H(14)ClN(3))(2)], the central Co(II) ion lies on a twofold rotation axis and adopts a distorted tetra­hedral coordination geometry defined by two N atoms from two 2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole ligands and two chloride anions. The Cl atom located in the side chain of the ligand is involved in inter­molecular C—H⋯Cl hydrogen bonding, which links neutral complex units into a one-dimensional right-handed helical chain running along a crystallographic 4(1) axis. Such hydrogen-bonded helical chains are connected to each other to form a homochiral three-dimensional supra­molecular network. One C atom of the 2-chloro­ethyl chain is disordered over two positions, with site-occupancy factors of 0.52 and 0.48.
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spelling pubmed-29618982010-12-30 Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II) Zhang, Zhong Zhao, Yao Geng, Zhi-Rong Wang, Zhi-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(12)H(14)ClN(3))(2)], the central Co(II) ion lies on a twofold rotation axis and adopts a distorted tetra­hedral coordination geometry defined by two N atoms from two 2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole ligands and two chloride anions. The Cl atom located in the side chain of the ligand is involved in inter­molecular C—H⋯Cl hydrogen bonding, which links neutral complex units into a one-dimensional right-handed helical chain running along a crystallographic 4(1) axis. Such hydrogen-bonded helical chains are connected to each other to form a homochiral three-dimensional supra­molecular network. One C atom of the 2-chloro­ethyl chain is disordered over two positions, with site-occupancy factors of 0.52 and 0.48. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961898/ /pubmed/21202795 http://dx.doi.org/10.1107/S1600536808018011 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhong
Zhao, Yao
Geng, Zhi-Rong
Wang, Zhi-Lin
Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title_full Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title_fullStr Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title_full_unstemmed Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title_short Dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κN]cobalt(II)
title_sort dichloridobis[2-(2-chloro­ethyl)-1,2,3,4-tetra­hydro­pyrazino[1,2-a]benzimidazole-κn]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961898/
https://www.ncbi.nlm.nih.gov/pubmed/21202795
http://dx.doi.org/10.1107/S1600536808018011
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