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Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II)
In the title compound, [Cu(C(7)H(3)NO(4))(C(6)H(6)N(2)O)(H(2)O)], the coordination geometry of the Cu(II) atom can be described as distorted square pyramidal. The basal plane is defined by one N atom and two O atoms from the deprotonated pyridine-2,6-dicarboxylate ligand, and a pyridyl N atom from...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961909/ https://www.ncbi.nlm.nih.gov/pubmed/21203078 http://dx.doi.org/10.1107/S1600536808019673 |
| _version_ | 1782189095001260032 |
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| author | Mutambi, E. M. |
| author_facet | Mutambi, E. M. |
| author_sort | Mutambi, E. M. |
| collection | PubMed |
| description | In the title compound, [Cu(C(7)H(3)NO(4))(C(6)H(6)N(2)O)(H(2)O)], the coordination geometry of the Cu(II) atom can be described as distorted square pyramidal. The basal plane is defined by one N atom and two O atoms from the deprotonated pyridine-2,6-dicarboxylate ligand, and a pyridyl N atom from the 4-pyridyl aldoxime ligand. The apical position is occupied by a water molecule. O—H⋯O hydrogen bonds lead to the formation of a two-dimensional network. |
| format | Text |
| id | pubmed-2961909 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619092010-12-30 Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) Mutambi, E. M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(3)NO(4))(C(6)H(6)N(2)O)(H(2)O)], the coordination geometry of the Cu(II) atom can be described as distorted square pyramidal. The basal plane is defined by one N atom and two O atoms from the deprotonated pyridine-2,6-dicarboxylate ligand, and a pyridyl N atom from the 4-pyridyl aldoxime ligand. The apical position is occupied by a water molecule. O—H⋯O hydrogen bonds lead to the formation of a two-dimensional network. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961909/ /pubmed/21203078 http://dx.doi.org/10.1107/S1600536808019673 Text en © E. M. Mutambi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mutambi, E. M. Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) |
| title | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) |
| title_full | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) |
| title_fullStr | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) |
| title_full_unstemmed | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) |
| title_short | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) |
| title_sort | aqua[4-(hydroxyiminomethyl)pyridine-κn
(1)](pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961909/ https://www.ncbi.nlm.nih.gov/pubmed/21203078 http://dx.doi.org/10.1107/S1600536808019673 |
| work_keys_str_mv | AT mutambiem aqua4hydroxyiminomethylpyridinekn1pyridine26dicarboxylatok3o2no6copperii |