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catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2) P:P′]
In the title chain compound, [Ag(NO(3))(C(26)H(24)P(2))](n), the bis(diphenylphosphino)ethane (dppe) units link the Ag(+) ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C—C bond and a twofold rotation axis p...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961910/ https://www.ncbi.nlm.nih.gov/pubmed/21203079 http://dx.doi.org/10.1107/S1600536808019442 |
| _version_ | 1782189095243481088 |
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| author | Wang, Xing-Cong Wu, Yan-Li You, Xiu-Li |
| author_facet | Wang, Xing-Cong Wu, Yan-Li You, Xiu-Li |
| author_sort | Wang, Xing-Cong |
| collection | PubMed |
| description | In the title chain compound, [Ag(NO(3))(C(26)H(24)P(2))](n), the bis(diphenylphosphino)ethane (dppe) units link the Ag(+) ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C—C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetrahedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°. |
| format | Text |
| id | pubmed-2961910 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619102010-12-30 catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2) P:P′] Wang, Xing-Cong Wu, Yan-Li You, Xiu-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title chain compound, [Ag(NO(3))(C(26)H(24)P(2))](n), the bis(diphenylphosphino)ethane (dppe) units link the Ag(+) ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C—C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetrahedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961910/ /pubmed/21203079 http://dx.doi.org/10.1107/S1600536808019442 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Xing-Cong Wu, Yan-Li You, Xiu-Li catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2) P:P′] |
| title |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
P:P′] |
| title_full |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
P:P′] |
| title_fullStr |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
P:P′] |
| title_full_unstemmed |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
P:P′] |
| title_short |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
P:P′] |
| title_sort | catena-poly[[(nitrato-κ(2)
o,o′)silver(i)]-μ-1,2-bis(diphenylphosphino)ethane-κ(2)
p:p′] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961910/ https://www.ncbi.nlm.nih.gov/pubmed/21203079 http://dx.doi.org/10.1107/S1600536808019442 |
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