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Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]]
The title compound, {Na(2)[Mg(2)(C(2)O(4))(3)(H(2)O)(2)]}(n), is isotypic with its Co analogue. There are two crystallographically independent oxalate groups in the asymmetric unit, one lying on an inversion center and the other on a general position. Mg(2+) ions are ligated by H(2)O molecules and...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961912/ https://www.ncbi.nlm.nih.gov/pubmed/21203081 http://dx.doi.org/10.1107/S1600536808019508 |
| _version_ | 1782189095709048832 |
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| author | Chen, Xue-An Song, Fang-Ping Chang, Xin-An Zang, He-Gui Xiao, Wei-Qiang |
| author_facet | Chen, Xue-An Song, Fang-Ping Chang, Xin-An Zang, He-Gui Xiao, Wei-Qiang |
| author_sort | Chen, Xue-An |
| collection | PubMed |
| description | The title compound, {Na(2)[Mg(2)(C(2)O(4))(3)(H(2)O)(2)]}(n), is isotypic with its Co analogue. There are two crystallographically independent oxalate groups in the asymmetric unit, one lying on an inversion center and the other on a general position. Mg(2+) ions are ligated by H(2)O molecules and bridged by tri- and tetradentate oxalate ligands, forming ladder-like double chains that are held together via O—H⋯O hydrogen bonds, with Na(+) cations located between the chains to balance the charge. |
| format | Text |
| id | pubmed-2961912 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619122010-12-30 Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] Chen, Xue-An Song, Fang-Ping Chang, Xin-An Zang, He-Gui Xiao, Wei-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {Na(2)[Mg(2)(C(2)O(4))(3)(H(2)O)(2)]}(n), is isotypic with its Co analogue. There are two crystallographically independent oxalate groups in the asymmetric unit, one lying on an inversion center and the other on a general position. Mg(2+) ions are ligated by H(2)O molecules and bridged by tri- and tetradentate oxalate ligands, forming ladder-like double chains that are held together via O—H⋯O hydrogen bonds, with Na(+) cations located between the chains to balance the charge. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961912/ /pubmed/21203081 http://dx.doi.org/10.1107/S1600536808019508 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Xue-An Song, Fang-Ping Chang, Xin-An Zang, He-Gui Xiao, Wei-Qiang Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title | Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title_full | Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title_fullStr | Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title_full_unstemmed | Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title_short | Poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(II)]] |
| title_sort | poly[disodium [diaquatri-μ(2)-oxalato-dimagnesium(ii)]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961912/ https://www.ncbi.nlm.nih.gov/pubmed/21203081 http://dx.doi.org/10.1107/S1600536808019508 |
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