Cargando…
Triaqua(3-carboxy-5-sulfonatobenzoato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate
In the title compound, [Co(C(8)H(4)O(7)S)(C(12)H(8)N(2))(H(2)O)(3)]·H(2)O, the Co(II) cation is coordinated by one sulfoisophthalate dianion, one bidentate phenathroline (phen) molecule and three water molecules in a distorted cis-CoN(2)O(4) octahedral geometry. In the crystal structure, aromatic...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961914/ https://www.ncbi.nlm.nih.gov/pubmed/21203083 http://dx.doi.org/10.1107/S1600536808019843 |
| _version_ | 1782189096188248064 |
|---|---|
| author | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_facet | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_sort | Zhang, Bing-Yu |
| collection | PubMed |
| description | In the title compound, [Co(C(8)H(4)O(7)S)(C(12)H(8)N(2))(H(2)O)(3)]·H(2)O, the Co(II) cation is coordinated by one sulfoisophthalate dianion, one bidentate phenathroline (phen) molecule and three water molecules in a distorted cis-CoN(2)O(4) octahedral geometry. In the crystal structure, aromatic π–π stacking occurs [centroid–centroid distances 3.7630 (14) and 3.7269 (15) Å], as well as an extensive O—H⋯O and C—H⋯O hydrogen-bonding network |
| format | Text |
| id | pubmed-2961914 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619142010-12-30 Triaqua(3-carboxy-5-sulfonatobenzoato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(4)O(7)S)(C(12)H(8)N(2))(H(2)O)(3)]·H(2)O, the Co(II) cation is coordinated by one sulfoisophthalate dianion, one bidentate phenathroline (phen) molecule and three water molecules in a distorted cis-CoN(2)O(4) octahedral geometry. In the crystal structure, aromatic π–π stacking occurs [centroid–centroid distances 3.7630 (14) and 3.7269 (15) Å], as well as an extensive O—H⋯O and C—H⋯O hydrogen-bonding network International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961914/ /pubmed/21203083 http://dx.doi.org/10.1107/S1600536808019843 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Triaqua(3-carboxy-5-sulfonatobenzoato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate |
| title | Triaqua(3-carboxy-5-sulfonatobenzoato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_full | Triaqua(3-carboxy-5-sulfonatobenzoato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_fullStr | Triaqua(3-carboxy-5-sulfonatobenzoato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_full_unstemmed | Triaqua(3-carboxy-5-sulfonatobenzoato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_short | Triaqua(3-carboxy-5-sulfonatobenzoato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_sort | triaqua(3-carboxy-5-sulfonatobenzoato-κo
(1))(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961914/ https://www.ncbi.nlm.nih.gov/pubmed/21203083 http://dx.doi.org/10.1107/S1600536808019843 |
| work_keys_str_mv | AT zhangbingyu triaqua3carboxy5sulfonatobenzoatoko1110phenanthrolinek2nncobaltiimonohydrate AT niejingjing triaqua3carboxy5sulfonatobenzoatoko1110phenanthrolinek2nncobaltiimonohydrate AT xuduanjun triaqua3carboxy5sulfonatobenzoatoko1110phenanthrolinek2nncobaltiimonohydrate |