Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate

The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol­ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl­ate O atoms, one ce...

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Detalles Bibliográficos
Autores principales: Yao, Sumei, Liu, Jianhua, Han, Qiuxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961916/
https://www.ncbi.nlm.nih.gov/pubmed/21203085
http://dx.doi.org/10.1107/S1600536808019806
Descripción
Sumario:The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol­ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl­ate O atoms, one central bridged O atom and one water mol­ecule, resulting in distorted FeO(6) octa­hedra. A network of O—H⋯O hydrogen bonds helps to establish the packing.

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