Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate

The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol­ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl­ate O atoms, one ce...

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Detalles Bibliográficos
Autores principales: Yao, Sumei, Liu, Jianhua, Han, Qiuxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961916/
https://www.ncbi.nlm.nih.gov/pubmed/21203085
http://dx.doi.org/10.1107/S1600536808019806
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author Yao, Sumei
Liu, Jianhua
Han, Qiuxia
author_facet Yao, Sumei
Liu, Jianhua
Han, Qiuxia
author_sort Yao, Sumei
collection PubMed
description The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol­ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl­ate O atoms, one central bridged O atom and one water mol­ecule, resulting in distorted FeO(6) octa­hedra. A network of O—H⋯O hydrogen bonds helps to establish the packing.
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spelling pubmed-29619162010-12-30 Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate Yao, Sumei Liu, Jianhua Han, Qiuxia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol­ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl­ate O atoms, one central bridged O atom and one water mol­ecule, resulting in distorted FeO(6) octa­hedra. A network of O—H⋯O hydrogen bonds helps to establish the packing. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961916/ /pubmed/21203085 http://dx.doi.org/10.1107/S1600536808019806 Text en © Yao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yao, Sumei
Liu, Jianhua
Han, Qiuxia
Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title_full Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title_fullStr Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title_full_unstemmed Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title_short Hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(III) nitrate acetic acid solvate
title_sort hexa-μ(2)-acetato-triaqua-μ(3)-oxido-triiron(iii) nitrate acetic acid solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961916/
https://www.ncbi.nlm.nih.gov/pubmed/21203085
http://dx.doi.org/10.1107/S1600536808019806
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AT liujianhua hexam2acetatotriaquam3oxidotriironiiinitrateaceticacidsolvate
AT hanqiuxia hexam2acetatotriaquam3oxidotriironiiinitrateaceticacidsolvate

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