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Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine lig...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961921/ https://www.ncbi.nlm.nih.gov/pubmed/21203090 http://dx.doi.org/10.1107/S1600536808019752 |
Sumario: | In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxylate O atoms from different 1,4-bdc ligands. The dicarboxylate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear Mn(II) clusters leads to a two-dimensional structure. |
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