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Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]

In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxyl­ate O atoms from different benzene-1,4-dicarboxyl­ate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine lig...

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Detalles Bibliográficos
Autores principales: Zhang, Wen-Zhi, Xu, Qun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961921/
https://www.ncbi.nlm.nih.gov/pubmed/21203090
http://dx.doi.org/10.1107/S1600536808019752
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author Zhang, Wen-Zhi
Xu, Qun
author_facet Zhang, Wen-Zhi
Xu, Qun
author_sort Zhang, Wen-Zhi
collection PubMed
description In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxyl­ate O atoms from different benzene-1,4-dicarboxyl­ate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxyl­ate O atoms from different 1,4-bdc ligands. The dicarboxyl­ate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear Mn(II) clusters leads to a two-dimensional structure.
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spelling pubmed-29619212010-12-30 Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] Zhang, Wen-Zhi Xu, Qun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxyl­ate O atoms from different benzene-1,4-dicarboxyl­ate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxyl­ate O atoms from different 1,4-bdc ligands. The dicarboxyl­ate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear Mn(II) clusters leads to a two-dimensional structure. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961921/ /pubmed/21203090 http://dx.doi.org/10.1107/S1600536808019752 Text en © Zhang and Xu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wen-Zhi
Xu, Qun
Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title_full Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title_fullStr Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title_full_unstemmed Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title_short Poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
title_sort poly[tris­(μ-benzene-1,4-dicarboxylato)bis­(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961921/
https://www.ncbi.nlm.nih.gov/pubmed/21203090
http://dx.doi.org/10.1107/S1600536808019752
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AT xuqun polytrismbenzene14dicarboxylatobisdipyrido32a23cphenazinetrimanganeseii