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Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine lig...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961921/ https://www.ncbi.nlm.nih.gov/pubmed/21203090 http://dx.doi.org/10.1107/S1600536808019752 |
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author | Zhang, Wen-Zhi Xu, Qun |
author_facet | Zhang, Wen-Zhi Xu, Qun |
author_sort | Zhang, Wen-Zhi |
collection | PubMed |
description | In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxylate O atoms from different 1,4-bdc ligands. The dicarboxylate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear Mn(II) clusters leads to a two-dimensional structure. |
format | Text |
id | pubmed-2961921 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619212010-12-30 Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] Zhang, Wen-Zhi Xu, Qun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(3)(C(8)H(4)O(4))(3)(C(14)H(8)N(4))(2)](n), one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxylate O atoms from different 1,4-bdc ligands. The dicarboxylate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear Mn(II) clusters leads to a two-dimensional structure. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961921/ /pubmed/21203090 http://dx.doi.org/10.1107/S1600536808019752 Text en © Zhang and Xu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Wen-Zhi Xu, Qun Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title | Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title_full | Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title_fullStr | Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title_full_unstemmed | Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title_short | Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)] |
title_sort | poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961921/ https://www.ncbi.nlm.nih.gov/pubmed/21203090 http://dx.doi.org/10.1107/S1600536808019752 |
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