Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate

The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa­hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole...

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Detalles Bibliográficos
Autores principales: Li, Xiuhua, Zuo, Ya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961922/
https://www.ncbi.nlm.nih.gov/pubmed/21203091
http://dx.doi.org/10.1107/S1600536808019326
Descripción
Sumario:The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa­hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole N atoms of the solvent mol­ecules, generating one-dimensional ladder motifs, and three inter­molecular C—H⋯S hydrogen bonds, forming a three-dimensional hydrogen-bonding network.

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