Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate

The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa­hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole...

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Detalles Bibliográficos
Autores principales: Li, Xiuhua, Zuo, Ya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961922/
https://www.ncbi.nlm.nih.gov/pubmed/21203091
http://dx.doi.org/10.1107/S1600536808019326
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author Li, Xiuhua
Zuo, Ya
author_facet Li, Xiuhua
Zuo, Ya
author_sort Li, Xiuhua
collection PubMed
description The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa­hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole N atoms of the solvent mol­ecules, generating one-dimensional ladder motifs, and three inter­molecular C—H⋯S hydrogen bonds, forming a three-dimensional hydrogen-bonding network.
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spelling pubmed-29619222010-12-30 Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate Li, Xiuhua Zuo, Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa­hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole N atoms of the solvent mol­ecules, generating one-dimensional ladder motifs, and three inter­molecular C—H⋯S hydrogen bonds, forming a three-dimensional hydrogen-bonding network. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961922/ /pubmed/21203091 http://dx.doi.org/10.1107/S1600536808019326 Text en © Li and Zuo 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiuhua
Zuo, Ya
Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title_full Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title_fullStr Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title_full_unstemmed Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title_short Di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κN)iron(II)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
title_sort di-μ-aqua-bis­[diaqua­bis(thio­cyanato-κn)iron(ii)] 4-(4-chloro­phen­yl)-1,2,4-triazole hexa­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961922/
https://www.ncbi.nlm.nih.gov/pubmed/21203091
http://dx.doi.org/10.1107/S1600536808019326
work_keys_str_mv AT lixiuhua dimaquabisdiaquabisthiocyanatoknironii44chlorophenyl124triazolehexasolvate
AT zuoya dimaquabisdiaquabisthiocyanatoknironii44chlorophenyl124triazolehexasolvate

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